Taylor ET, Wirmvem MJ, Sawyerr VH and Nakai S
Eleven airborne PM2.5 PAH concentrations were characterized in the kitchen, outdoor and living room environments in households that burn wood and charcoal fuels in Western Sierra Leone, during a survey that was conducted in September 2011. The average concentration of total PAHs (Σ11PAHs) was 1279.7 ng/m3 in kitchen, 41.2 ng/m3 in outdoor, 19.8 ng/m3 in living room for households burning wood while those burning charcoal was 96.5 ng/m3, 13.1 ng/ m3 and 8.9 ng/m3 in the kitchen, outdoor and living room, respectively. The percentage contribution of higher molecular weight PAHs to Σ11PAHs was about 25% higher compared to medium molecular weight PAHs for either household category in all three locations, with a somewhat different scenario for kitchens with wood stove. The ratio of indoor/ outdoor air of Σ11PAHs showed considerable variation among households burning charcoal (p=0.0021; t-test) relative to those burning wood, attributed to non-prolonged equilibrium between the two environments. Benzo(a)pyrene (BaP) equivalency results revealed that BaP and dibenzo(a,h)anthracene were the two most dominant compounds that contributed to more than 90% of the total carcinogenicity in all three environments for households burning wood and charcoal. The results suggest that kitchens, where biomass fuels are burnt continue to be a hazardous place for people of developing countries to spend their time.
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